1.         Calculate the number of moles in each of the following masses:

  1. 0.039g of palladium                =          3.665×10-4 moles
  1. 0.0073kg of tantalum
  1. 3.37 x 10-6 g of molybdenum              =          3.513×10-8 moles
  1. 1.06 x 1023 atoms of tungsten
  1. 3.008 x 1019 atoms of silver                =          4.997×10-5 moles
  1. 7.04g of Lead (II) Nitrate,  Pb(NO3)2

Molar mass =331.2 g/mol

Moles =  0.0213 moles

  1. 0.00322g of stearic acid,  C17H35COOH
  1. 5000Kg of Iron(III) Oxide, Fe2O3

2.         Calculate the number of atoms in each of the following:

  1. 17.0 mol of germanium
  1. 0.0019 mol of zirconium
  1. 812g of gold                           atoms = 2.482×1024
  1. 2.00 x 102 mg of americium
  1. 10.09 kg of neon

3.         Calculate the mass of each of the following:

  1. 550 mol of aluminium
  1. 7 mol of titanium
  1. 0.0091 mol of retinoic acid, C20H28O2
  1. 12.0 mol of ethylamine, C2H5NH2
  1. 9.96 x 1026 atoms of tellurium
  1. 2.94 x 1017 atoms of hafnium

4.         Calculate the number of molecules in each of the following:  moles x Avog # = molec.

  1. 4.27 mol of tungsten(VI) oxide, WO3

4.27mol x 6.02×1023 = 2.571×1024

  1. 72.5 mol of toluene, C6H5CH3
  1. 1500 mol of hydrazine, N2H4
  1. 285g of Iron (III) phosphate, FePO4 First find molar mass.  Second,

Convert g of FePO4 to moles of FePO4 and then multiply moles x Avog. #  =

  1. 4.6 x 10-4g of mercury (II) acetate, Hg(C2H3O2)2

5. Calculate the number of specified atoms in each of the following:

  1. Tungsten in 4.27 mol of tungsten(VI) oxide, WO3 =          2.5705×1024 atoms
  1. Carbon in 72.5 mol of toluene, C6H5CH3 =          3.0552×1026 atoms
  1. Hydrogen in 1500 mol of hydrazine, N2H4 =          3.612×1027 atoms
  1. Oxygen in 285g of Iron (III) phosphate, FePO4
  1. Hydrogen in 4.6 x 10-4g of mercury (II) acetate, Hg(C2H3O2)2

6.         Calculate the percentage of the given element or molecule in each:

  1. nitrogen in urea, NH2CONH2 %N=(28/60)x100=46.67%
  1. sulfur in sulfuryl chloride, SO2Cl2 32.18%
  1. bromine in calcium bromide, CaBr2 79.95%
  1. water in sodium chloride hexahydrate, SrCl2.6H2O               40.52%
  1. water in beryllium nitrate trihydrate, Be(NO3)2.3H2O           28.88%

7.         Cinnabar is a mineral that is mined in order to produce mercury.  Cinnabar is mercury (II) sulfide, HgS.  What mass of mercury can be obtained from 50g.

8.         A sample of Ag2S has a mass of 62.4g.  what mass of each element could be obtained by decomposing this sample?

9.         Determine the Empirical Formula for the following:

  1. 28.4% copper, 71.6% bromine                        CuBr2
g based on 100g sample moles
Cu 28.4g 0.447 1
Br 71.6g 0.896 2
  1. 39.0% potassium,12.0% carbon, 1.01 %  hydrogen,  48.0% oxygen.

The data was corrected

KHCO3

  1. 77.3% silver, 7.4% phosphorous, 15.3% oxygen

Ag3PO4

10.       Calculate the mass of the given element in each of the following:

  1. Chromium in 1.00 kg sodium dichromate (Na2Cr2O7)           397g

First Find % Cr in the compound    (that is % composition of Cr)

Second, multiply the % times 1000g of the Na2Cr2O7.

  1. Nitrogen in 85.0 mg of the amino acid lysine, C6H14N2O3 16.3mg
  1. Cobalt in 2.84 g of cobalt(II) acetate, Co(C2H3O2)2 0.945g

11.       Determine the empirical formula for compounds that have the following analyses

a.         28.4% copper, 71.6% bromine                                                CuBr2

b.         39.0% potassium, 12.0% carbon, 1.01% hydrogen, 47.9% Oxygen   KHCO3

c.         77.3% silver, 7.4% phosphorous, 15.3% oxygen                             Ag3PO4

d.         0.57% hydrogen, 72.1% iodine, 27.3% oxygen                              HIO3

12.       Determine the molecular formula of each unknown substance:

a.         Empirical formula CH2 and experimental molar mass 28g/mol          C2H2

b.         Empirical formula C2HCl and experimental molar mass 179g/mol    C6H3Cl3

c.         Empirical formula C6H8O and experimental molar mass 290g/mol      C18H24O3

13.       A 0.400g sample of a white powder contains 0.141g of potassium, 0.115g of sulfur and 0.144g of oxygen.  What is the empirical formula for the compound?

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